Medical emergency?Emergency? Call 911. Nearest emergency roomsNearest ERs

Anesthesiology

Donald J. Cain Iii, MD

Works at hospitals in Pensacola, FL · Florida

Summary

Dr. Donald J. Cain Iii, MD is an anesthesiologist at 8300 Collier Blvd, Naples, FL 34114. Phone: (239) 354-6000. Accepts Medicare assignment. In 2024, Donald J. Cain Iii had 22 Original Medicare patients and 29 services. NPI 1669404729. Source: CMS National Downloadable File, updated October 2, 2026; CMS Facility Affiliation Data, updated October 2, 2026; CMS Medicare Physician & Other Practitioners, data year 2024.

  • Specialty: Anesthesiologist (Medicare lists Anesthesiology)
  • Address: 8300 Collier Blvd, Naples, FL 34114 · Directions (1 more location)
  • Phone: (239) 354‑6000
  • Medicare: Accepts Medicare assignment
  • Hospital: HCA Florida West Hospital
  • Group practice: Capital Anesthesia Solutions of Florida II, LLC (+1 more)
  • Medical school: graduated 1995 (31 years since medical school)
  • Gender (as listed): Male

From official Medicare data

This page shows what Medicare's official clinician data says about Donald J. Cain Iii, joined by NPI number (data updated October 2, 2026). It is not a recommendation or a rating. Call the office or hospital to confirm before you go.

In a medical emergency, call 911.

Quick answers

Does Donald J. Cain Iii accept Medicare assignment?
Yes. Medicare's clinician data says Donald J. Cain Iii accepts Medicare assignment (the Medicare-approved amount as full payment for covered services), as of October 2, 2026. Ask the office to confirm before your visit.
How many Medicare patients does Donald J. Cain Iii see?
In 2024, CMS data shows 22 Original Medicare patients and 29 services for Donald J. Cain Iii. This counts Original Medicare only and measures volume, not quality.
What is Donald J. Cain Iii's NPI number?
1669404729. The NPI (National Provider Identifier) is the clinician's permanent federal ID; you can look it up in the official NPI Registry.

Medicare activity in 2024

Official CMS public-use data for Donald J. Cain Iii, data year 2024 (released May 21, 2026). It covers Original Medicare (fee-for-service) patients only, not Medicare Advantage or other insurance. It shows volume, not quality or outcomes. CMS hides any count of 10 or fewer patients.

Original Medicare patients22
Services billed to Medicare29
Different services or procedures15
Participating Medicare providerYes
Average age of these patients76

Chronic conditions among these patients

Share of this clinician’s Original Medicare patients with each condition, as published by CMS (it describes the patients, not the care given).

  • High blood pressure75%
  • High cholesterol75%
  • Arthritis59%
  • Ischemic heart disease55%

Hospitals where Donald J. Cain Iii works

Medicare's Facility Affiliation Data lists Donald J. Cain Iii at these hospitals (updated October 2, 2026). Each hospital page shows its address, phone, emergency services, Medicare rating and all its clinicians. Star rating and emergency services: Hospital General Information (CMS), data updated October 26, 2026.

Practice locations

Addresses where Donald J. Cain Iii is enrolled with Medicare (CMS data updated October 2, 2026).

Group practices

Medicare enrollment lists Donald J. Cain Iii as a member of these groups (CMS data updated October 2, 2026).

  • Capital Anesthesia Solutions of Florida II, LLC355 clinicians in the group
  • Anesthesia Physician Solutions of North Florida LLC278 clinicians in the group

Specialties

Find other Anesthesiology doctors in Florida →

Other anesthesiologists in Naples

Clinicians with the same Medicare primary specialty in Naples, FL — not a recommendation.

All anesthesiologists in Naples →

Other clinicians in Capital Anesthesia Solutions of Florida II, LLC

Medicare enrollment lists these clinicians in the same group practice — not a recommendation.

Clinician information

CredentialMD
Graduation year1995 (31 years since medical school)
Gender (as listed)Male
Medicare assignmentAccepts (Medicare-approved amount as full payment)
NPI (National Provider Identifier)1669404729
CorrectionsReport an error or suggest an update →

Most corrections must be made at the source: clinicians update their NPI Registry record (NPPES) and their Medicare enrollment (PECOS); this page follows the next data release.

Sources

  1. Facility Affiliation Data — Centers for Medicare & Medicaid Services (CMS), data updated October 2, 2026, retrieved October 29, 2026
  2. Hospital General Information — CMS, data updated October 26, 2026, retrieved November 13, 2026
  3. National Downloadable File (Doctors and Clinicians) — CMS, data updated October 2, 2026, retrieved October 29, 2026
  4. Medicare Physician & Other Practitioners - by Provider — CMS, data year 2024, released May 21, 2026; Medicare Physician & Other Practitioners - by Provider and Service
  5. NPI Registry — U.S. Department of Health and Human Services (NPPES), the clinician’s official record
  6. Medicare Care Compare — official Medicare tool to look up clinicians